A rich mixture will prevent the plugs from firing. The injectors keep adding more fuel which, believe it or not, will exit the cylinder through the, wait for it, the exhaust valve when the cam opens it. Bottom line is that it is perfectly normal for unburned fuel to get into the exhaust system.
If there is enough fuel in the cylinders, some of it will get past the rings and into the crankcase. Speaking of rings, have you done a compression check to see if they are sealing properly. Lack of good compression may possibly cause some of the symptoms you are seeing.